Bis(2-iminomethyl-5-methoxyphenolato)nickel(II)
نویسنده
چکیده
The title compound, [Ni(C(8)H(8)NO(2))(2)], is a centrosymmetric mononuclear nickel(II) complex. The Ni(II) ion, lying on an inversion centre, is four-coordinated in a square-planar geometry by two phenolate O and two imine N atoms from two symmetry-related 2-imino-methyl-5-methoxy-phenolate ligands. In the crystal, mol-ecules are linked into corrugated layers parallel to (100) by N-H⋯O hydrogen bonds.
منابع مشابه
Bis{2-[3-(dimethylamino)propyliminomethyl]-6-methoxyphenolato-κ3 N,N′,O 1}nickel(II)
The centrosymmetric title complex, [Ni(C(13)H(19)N(2)O(2))(2)], is a mononuclear nickel(II) complex. The Ni(II) atom is coordinated by four N atoms and two O atoms of two deprotonated Schiff base ligands, forming a slightly distorted octa-hedral coordination configuration, in which the tertiary N atoms occupy the axial positions.
متن کاملBis(2-hydroxyiminomethyl-6-methoxyphenolato-κ2 O 1,N)nickel(II)
The Ni atom in the title compound, [Ni(C(8)H(8)NO(3))(2)], lies on a center of inversion in a square-planar coordination enviroment. The hydroxyl group of one anion forms a short hydrogen bond to the metal-coordinated O atom of the other anion.
متن کاملBis[2-(cyclohexyliminomethyl)-5-methoxyphenolato]copper(II)
In the title centrosymmetric mononuclear complex, [Cu(C(14)H(18)NO(2))(2)], the Cu(II) ion, lying on an inversion centre, is four-coordinated by two imine N and two phenolate O atoms from two Schiff base ligands, forming a slightly distorted square-planar geometry.
متن کاملBis{2-[2-(isopropylammonio)ethyliminomethyl]-6-methoxyphenolato}nickel(II) dithiocyanate
The title complex, [Ni(C(13)H(20)N(2)O(2))(2)](NCS)(2), consists of a centrosymmetric mononuclear four-coordinate nickel(II) complex cation and two thio-cyanate anions. The Ni atom is located on an inversion center and is coordinated by two phenol O atoms and two imine N atoms from two equivalent Schiff base ligands, in a square-planar geometry. In the crystal structure, the amino H atoms are i...
متن کاملBis[2-(cyclopropyliminomethyl)-5-methoxyphenolato]zinc(II)
In the title complex, [Zn(C(11)H(12)NO(2))(2)], the Zn(2+) ion (site symmetry 2) is coordinated by two N,O-bidentate Schiff base ligands, generating a tetra-hedral ZnO(2)N(2) geometry for the metal ion.
متن کاملذخیره در منابع من
با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید
عنوان ژورنال:
دوره 65 شماره
صفحات -
تاریخ انتشار 2009